So update. I did a fresh windows in install on my second SSD (Also wiped my first) and it seems to be working now. Oddly enough though, despite having just downloaded steam (b/c of the fresh download), I'm getting a steam service/vac error on CSGO... I'm pretty sure I fixed that though (Had to run some Steam Service repair file).
tl:dr: It works now but if it isn't one thing, it's another.