Also Ted Bavaria is bad. Only 33,000 troops. Who even cares if their some of the most highly trained soldiers in Germany
Nope, that's wrong. 33.000 marched to Russia, however the Bavarian Army had about 60.000-65.000 men alone in the professional army, they were able to raise even more men for the field while keeping the nation going when needed. Let's not forget that Bavaria rekt Austria hard.... Since 1805 Bavaria had to bring up 30.000 men for the French cause all the time, but the Bavarian army itself was much larger.
These are the infantry divisions that marched to Russia in 1812:
19. Division General Deroy (Generalstab: Major von Gravenreuth)1. Brigade Generalmajor von Siebein1. Leichtes Infanteriebataillon (Major Gedoni) 16 Offiziere - 581 Mann
1. Linieninfanterie-Regiment König (Oberst Baron Ströhl) 38 Offiziere - 1.514 Mann
9. Linieninfanterie-Regiment Ysenburg (Oberst de la Motte) 41 Offiziere - 1.507 Mann
2. Brigade Generalmajor von Raglovich3. Leichtes Infanteriebataillon (Major Bernklau) 19 Offiziere - 745 Mann
4. Linieninfanterie-Regiment Sachsen-Hildburghausen (Oberst von Zoller) 39 Offiziere - 1.444 Mann
10. Linieninfanterie-Regiment Junker (Oberst Graf Preysing) 37 Offiziere - 1.473 Mann
3. Brigade Generalmajor Graf Rechberg6. Leichtes Infanteriebataillon (Major La Roche) 20 Offiziere - 1.009 Mann
8. Linieninfanterie-Regiment Herzog Pius (Oberst Wreden) 37 Offiziere - 1.272 Mann
20. Division General Graf von Wrede (Generalstab: Oberst von Comeau)1. Brigade Generalmajor von Vincenti (später Generalmajor Minucci)2. Leichtes Infanteriebataillon (Major Treuberg) 21 Offiziere - 710 Mann
2. Linieninfanterie-Regiment Kronprinz (Oberst Graf Spaur) 41 Offiziere - 1.513 Mann
6. Linieninfanterie-Regiment Herzog Wilhelm (Oberst von Deroy) 36 Offiziere - 1.528 Mann
2. Brigade Generalmajor Beckers (später Generalmajor von Vincenti)4. Leichtes Infanteriebataillon (Major Theobald) 19 Offiziere - 732 Mann
3. Linieninfanterie-Regiment Prinz Carl (Oberst Graf Waldkirch) 37 Offiziere - 1.508 Mann
7. Linieninfanterie-Regiment Löwenstein-Werthheim (Oberst Maillot de la Treille) 37 Offiziere - 1.481 Mann
3. Brigade Oberst Baron Habermann5. Leichtes Infanteriebataillon (Major Buttler) 13 Offiziere - 460 Mann
5. Linieninfanterie-Regiment Preysing (Oberst Baron Habermann) 39 Offiziere - 1.504 Mann
11. Linieninfanterie-Regiment Kinkel (Oberst Graf Dallwigk) 39 Offiziere - 1.528 Mann
Both Divisions also had cavalry and artillery, I could not find the exact numbers though. However, all in all 33.000 men as you said - after years of war, let's not forget this!
However the infantry regiments went to Russia with one batallion out of two only, the other one was kept in Bavaria. That means that more then 20.000 additional men of the professional line infantry were stationed in Bavaria to be able to defend the homeland against a possible Austrian attack.
Earlier in 1809 the Bavarian army consisted out of the following troops:
13 Linien-Infanterie-Regimentern
12 Reserve-Bataillons
7 leichten Infanterie-Bataillons
2 freiwilligen Jäger-Bataillons zu Fuß
1 freiwilligen Jäger-Corps zu Pferd
2 Dragoner-Regimenter
4 Chevauxlegers-Regimenter
20 Batterien Artillerie.
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Summing up to about 55.000-60.000 professional soldiers
+ The Royal Guards with about 3000 men, both cavalry and infantry
+ The Gendarmerie with about 2000 men, both cavalry and infantry
+ Professional Mountain-Riflemen (Gebirgsschützen, about 7000 men).
+ The National Militia (Every man up to 40)
Bavaria also was much more advanced in the cultural and technical sector then Austria or Russia, the Electorate and later Kingdom of Bavaria was very very modern and the FIRST ONE to have cartographed a full detailed map of itself.
So, to end it: As I said, Bavaria was much stronger then most people know. The German States had the most citizens in all Europe. If they were united in one state they would have easily been the major power in the world.